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Heavy on low cost cards to get the deck rolling fast, win con being either pyromancer's going off with bolts to the face or infinite splinter/exarch combo. Unsure on sideboard, definitely thinking Mana Leak for when Mental Misstep has no application. Also do note that in the mana curve, the 1 phyrexian mana cards are counted as 2 mana.
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i am not quite sure what you plan on countering with mental misstep. and because it is a combo deck, and you don't seem to be using any alternate win cons, I would add the 4th splinter twin.
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Actually I have 2 call to minds and 4 pyromancer's ascension and in my playtesting I do pretty well rotating lightning bolts with copies if I don't manage to get my deceiver/twin combo going. As for why to not run the fourth twin, the twin is a dead card without the deceiver, and I have no other card that really benefits from it, even if twinning a spellskite would have some definite funny value drawing their spells onto a clone. Mental Misstep will counter some combo dissruptive cards, including mental misstep, spell pierce, IOK, Duress, Fog, and surgical extraction.
Jace? Halimer depths are good though...
The way the deck plays, I could see big Jace being pretty helpful but ohh god that sounds like it will set my wallet on fire. Little Jace is a little insignificant in power compared to just running normal instant/sorcery draw with pyromancers though.